Has the user tried hitting the OK button in the email? According to the userResource.java file in <Windchill>/src/com/ptc/netmarkets/users, this message means that the email address that was used to invite this user to the project is different from the email address on the user's Windchill account. The email is sent out to verify that both email addresses belong to the same user. Hitting OK should prevent the email from being sent to that user in the future.
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