If you look at the "LDAP erorr code 32 No Such Object" error in the Method Server log, does it show what object it's looking for and not able to find? Since this user is disconnected, Windchill shouldn't be looking for the user itself. It must be looking for some other LDAP object. If you delete/reconnect that LDAP object first, then you should be able to delete the user.
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